Cover Feature: Liquid‐Phase Cyclohexene Oxidation with O2 over Spray‐Flame‐Synthesized La1−xSrxCoO3 Perovskite Nanoparticles (Chem. Eur. J. 68/2021)

Cover Feature: Liquid‐Phase Cyclohexene Oxidation with O2 over Spray‐Flame‐Synthesized La1−xSrxCoO3 Perovskite Nanoparticles (Chem. Eur. J. 68/2021)

The liquid‐phase oxidation of cyclohexene was studied over a series of Sr‐substituted La1−xSrxCoO3 catalysts of perovskite structure under mild reaction conditions with O2 as oxidant in an autoclave. The substitution of Sr into the perovskite structure led to the formation of catalytically active ox...

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Bibliographic Details
Published in:Chemistry : a European journal Vol. 27; no. 68; p. 16807
Main Authors: Büker, Julia, Alkan, Baris, Chabbra, Sonia, Kochetov, Nikolai, Falk, Tobias, Schnegg, Alexander, Schulz, Christof, Wiggers, Hartmut, Muhler, Martin, Peng, Baoxiang
Format: Journal Article
Language:English
Published: 06-12-2021
Subjects:
Cyclohexene hydroperoxide
flame-spray synthesis
in situ ATR-IR
oxygen vacancies
spin trap EPR
Sr doping
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Summary:The liquid‐phase oxidation of cyclohexene was studied over a series of Sr‐substituted La1−xSrxCoO3 catalysts of perovskite structure under mild reaction conditions with O2 as oxidant in an autoclave. The substitution of Sr into the perovskite structure led to the formation of catalytically active oxygen species. In‐situ ATR IR measurements provided a comprehensive insight into the reaction mechanism under oxidation reaction conditions. More information can be found in the Full Paper by H. Wiggers, B. Peng et al. (DOI: 10.1002/chem.202103381).
Bibliography:These authors contributed equally to this work.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.202103785