Recovery of zinc from galvanized scraps

• Published in: Turkish journal of engineering & environmental sciences Vol. 26; no. 5; pp. 395 - 402
• Main Authors: AKTAŞ, Serdar, AÇMA, Ercan
• Format: Journal Article
• Language: English
• Published: 2002
• Subjects: electrochemistry; Elektrokimya; Fizikokimya; Galvanize çelik; Galvanized steel; Geri kazanım; Hurda; impurity; Kinetics; Kinetik; Metal Bilimi; Metal Eritme ve Saflaştırma; Metal İşleme Teknolojisi; Metal Working Technology; Physical Chemistry; precipitation[phase separation]; recovery; Safsızlık; Science of Metals; scrap; Sıyırma; Smelting and Refining of Metals; stripping; zinc; Çinko; Çöktürme[faz ayrılması]
• ISSN: 1300-0160

The stripping of Zn in sulfuric acidic solutions from galvanized steel products obtained from industry and the removal of impurities from this solution and the conditions required for Zn recovery were experimentally investigated. According to the results,it is possible to completely strip Zn from used galvanized steel products by using sulfuric acid with a pH value of up to 0.2. A solution that contains Zn over 80-85 g/l and Fe 0.2 g/l can be produced by repeated stripping and it is possible to obtain $ZnSO_4$ from the solution by adding volatile liquid (ethyl alcohol). The precipitated Zn compound is $ ZnSO_4$.$H_2O$. This compound contains 36.4% Zn and 0.002% Fe and is a raw material pure enough for commercial use. The ethyl alcohol used to obtain $ZnSO_4$.$H_2O$ from the rich stripping solution is recovered with 90% efficiency through distillation at $78^\circ C$ for 20 min. This process optimized by the experiments allows for the manufacture of saleable products and causes no environmental problems.