Sliding twin-domains in self-heated needle-like VO 2 single crystals

The prototypical metal-insulator transition in VO at 340 K is from a high-temperature rutile phase to a low-temperature monoclinic phase. The lower symmetry of the monoclinic structure removes the degeneracy of the two equivalent directions of the tetragonal structure, giving rise to twin domains. S...

Full description

Saved in:
Bibliographic Details
Published in:Scientific reports Vol. 10; no. 1; p. 6833
Main Authors: Fisher, Bertina, Patlagan, Larisa, Reisner, George M
Format: Journal Article
Language:English
Published: England 22-04-2020
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The prototypical metal-insulator transition in VO at 340 K is from a high-temperature rutile phase to a low-temperature monoclinic phase. The lower symmetry of the monoclinic structure removes the degeneracy of the two equivalent directions of the tetragonal structure, giving rise to twin domains. Since formation of domain walls require energy most needle-like monoclinic single crystal are single-domain. The mixed metal-insulator state in self-heated needle-like single crystals exhibits various domain patterns, the most remarkable being static insulating triangular domains embedded in the metal and narrow insulating domains sliding along the metallic background in the direction of the electric current. Reported here are results obtained for some rare needle-like twinned VO single crystals. Such sample revealed a unique feature: joint static triangular twins emit sliding twin domains, first overlapping and later disjoining. Dark and bright twins and dim metallic background were seen for optimal orientation under a microscope, due to polarization by reflection.
ISSN:2045-2322