Water Uptake and Transport Properties of La 1-x Ca x ScO 3-α Proton-Conducting Oxides

• Published in: Materials Vol. 12; no. 14
• Main Authors: Lesnichyova, Alyona, Stroeva, Anna, Belyakov, Semyon, Farlenkov, Andrey, Shevyrev, Nikita, Plekhanov, Maksim, Khromushin, Igor, Aksenova, Tatyana, Ananyev, Maxim, Kuzmin, Anton
• Format: Journal Article
• Language: English
• Published: Switzerland 10-07-2019
• Subjects: proton conductivity and proton mobility; LaScO3; water uptake; defect structure
• ISSN: 1996-1944; 1996-1944

In this study, oxide materials La
Ca
ScO
(x = 0.03, 0.05 and 0.10) were synthesized by the citric-nitrate combustion method. Single-phase solid solutions were obtained in the case of calcium content x = 0.03 and 0.05, whereas a calcium-enriched impurity phase was found at x = 0.10. Water uptake and release were studied by means of thermogravimetric analysis, thermodesorption spectroscopy and dilatometry. It was shown that lower calcium content in the main phase leads to a decrease in the water uptake. Conductivity was measured by four-probe direct current (DC) and two-probe ascension current (AC) methods at different temperatures,
O
and
H
O. The effects of phase composition, microstructure and defect structure on electrical conductivity, as well as correlation between conductivity and water uptake experiments, were discussed. The contribution of ionic conductivity of La
Ca
ScO
rises with decreasing temperature and increasing humidity. The domination of proton conductivity at temperatures below 500 °C under oxidizing and reducing atmospheres is exhibited. Water uptake and release as well as transport properties of La
Ca
ScO
are compared with the properties of similar proton electrolytes, La
Sr
ScO
, and the possible reasons for their differences were discussed.