Electrical properties of Bi(2)TiO(5) ceramic

Electrical properties of polycrystalline Bi(2)TiO(5) ceramic, prepared by a high-temperature solid-state reaction technique, were studied by using complex impedance spectroscopy. Preliminary structural analysis shows the formation of a new compound with an orthorhombic crystal structure at room temp...

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Bibliographic Details
Published in:Journal of alloys and compounds Vol. 490; no. 1-2; pp. 589 - 593
Main Authors: Yadav, Yogendra Kumar, Sahoo, M.P.K., Choudhary, R.N.P.
Format: Journal Article
Language:English
Published: 04-02-2010
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Summary:Electrical properties of polycrystalline Bi(2)TiO(5) ceramic, prepared by a high-temperature solid-state reaction technique, were studied by using complex impedance spectroscopy. Preliminary structural analysis shows the formation of a new compound with an orthorhombic crystal structure at room temperature. The spectroscopic data presented in impedance plane show the grain and grain boundary contributions towards electrical processes in the form of semi-circular arcs. A detailed analysis of the arcs reveals the presence of a parallel resistance and capacitance in series with a parallel resistance and constant phase element as an equivalent electrical circuit. The inclusion of constant phase element in the equivalent circuit is supported by Johnscher's power law. The dc conduction through Bi(2)TiO(5) reflects a series layer model (i.e., arrangement of capacitors in a series fashion) for the microstructure.
Bibliography:ObjectType-Article-2
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ISSN:0925-8388
DOI:10.1016/j.jallcom.2009.10.092