Controlled Atomic Doping of a Single Csub 60 Molecule

We report a method for controllably attaching an arbitrary number of charge dopant atoms directly to a single, isolated molecule. Charge-donating K atoms adsorbed on a silver surface were reversibly attached to a Csub 60 molecule by moving it over K atoms with a scanning tunneling microscope tip. Sp...

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Bibliographic Details
Published in:Science (American Association for the Advancement of Science) Vol. 304; no. 5668; pp. 281 - 284
Main Authors: Yamachika, R, Grobis, M, Wachowiak, A, Crommie, M F
Format: Journal Article
Language:English
Published: 09-04-2004
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Summary:We report a method for controllably attaching an arbitrary number of charge dopant atoms directly to a single, isolated molecule. Charge-donating K atoms adsorbed on a silver surface were reversibly attached to a Csub 60 molecule by moving it over K atoms with a scanning tunneling microscope tip. Spectroscopic measurements reveal that each attached K atom donates a constant amount of charge (~0.6 electron charge) to the Csub 60 host, thereby enabling its molecular electronic structure to be precisely and reversibly tuned. [PUBLICATION ABSTRACT]
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ISSN:0036-8075