1,3-Phosphorotropic migration in the C super(3)NC super(5) triad of 1,4-benzodiazepines accompanied by isomerization of Ph sub(2)POC super(3)NC super(5) to Ph sub(2)P(O)C super(5)NC super(3)

1,3-Phosphorotropic migration in the C super(3)NC super(5) triad of 1,4-benzodiazepines accompanied by isomerization of Ph sub(2)POC super(3)NC super(5) to Ph sub(2)P(O)C super(5)NC super(3)

It is demonstrated that phosphorotropic migration occurs in the C super(3)NC super(5) triad of 1,4-benzodiazepines, which is accompanied by the isomerization of Ph sub(2)POC super(3) to Ph sub(2)P(O)C super(5).

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Bibliographic Details
Published in:Tetrahedron letters Vol. 55; no. 35; pp. 4879 - 4882
Main Authors: Gololobov, Yuri G, Krasnova, Irina Yu, Barabanov, Sergei V, Khrustalev, Viktor N, Andronati, Sergei A, Pavlovsky, Viktor I
Format: Journal Article
Language:English
Published: 27-08-2014
Subjects:
Isomerization
Migration
Tetrahedrons
Online Access:Get full text
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Summary:It is demonstrated that phosphorotropic migration occurs in the C super(3)NC super(5) triad of 1,4-benzodiazepines, which is accompanied by the isomerization of Ph sub(2)POC super(3) to Ph sub(2)P(O)C super(5).
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ISSN:0040-4039
DOI:10.1016/j.tetlet.2014.07.010