Influences of carbon content and coating carbon thickness on properties of amorphous CoSnO3 composites as anode materials for lithium-ion batteries

• Published in: Applied surface science Vol. 311; pp. 484 - 489
• Main Authors: Fan, Fuqiang, Fang, Guoqing, Zhang, Ruixue, Xu, Yanhui, Zheng, Junwei, Li, Decheng
• Format: Journal Article
• Language: English
• Published: 01-08-2014
• Subjects: Carbon; Carbon content; Coating; Diffraction; Glucose; Lithium-ion batteries; Optimization; X-ray diffraction
• ISSN: 0169-4332
• DOI: 10.1016/j.apsusc.2014.05.094

A series of core-shell carbon coated amorphous CoSnO3 (CoSnO3) with different carbon content are synthesized. Effects of carbon content and coating carbon thickness on the physical and electrochemical performances of the samples were studied in detail. The samples were analyzed by X-ray diffraction (XRD), transmission electron microscopy (TEM), thermal gravimetric analysis (TGA), galvanostatic charge-discharge and AC impedance spectroscopy, respectively. The results indicate that controlling the concentration of aqueous glucose solution influences the generation of in-situ carbon layer thickness. The optimal concentration of aqueous glucose solution, carbon content and carbon layer thickness are suggested as 0.25M, 35.1% and 20nm, respectively. CoSnO3 composite prepared under the optimal conditions exhibits excellent cycling performance, whose reversible capacity could reach 491mAhg-1 after 100 cycles.