Synthesis of cadmium selenide-gold hybrid nanorods

In this work, we reported the synthesis of cadmium selenide-gold (CdSe-Au) hybrid nanorods. The growth substrates, CdSe nanorods, were synthesized using a simple mono-injection method. The growth models for CdSe with different morphologies were proposed, and validated by the experimental results. It...

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Bibliographic Details
Main Author: Jia, Xiaoxiong
Format: Dissertation
Language:English
Published: ProQuest Dissertations & Theses 01-01-2011
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Summary:In this work, we reported the synthesis of cadmium selenide-gold (CdSe-Au) hybrid nanorods. The growth substrates, CdSe nanorods, were synthesized using a simple mono-injection method. The growth models for CdSe with different morphologies were proposed, and validated by the experimental results. It can be briefly described as concentrated CdSe monomers were prone to forming isotropic CdSe nanoparticles; while diluted CdSe monomers were prone to forming anisotropic CdSe nanorods. The growth of Au nanoparticles on the surface of CdSe nanorods was achieved via galvanic replacement reactions between Au ions (AuCl3) and CdSe nanorods at room temperature. By adjusting the reaction times, the sizes of Au nanoparticles could be tuned from 1.7 ± 0.6 nm to 2.4 ± 0.9 nm.
ISBN:9781267060501
1267060506