Oxalic Acid-catalyzed Reaction of Alcohols with NaSCN
Oxalic acid-mediated conversion of alcohols to thiocyante and/or isothiocyanate is described. Aliphatic tertiary alcohols give isothiocyanate by the reaction with NaSCN in the presence of I2, whereas they give thiocyanate without it.
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| Published in: | Chemistry letters Vol. 35; no. 11; p. 1262 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Tokyo
Chemical Society of Japan
01-11-2006
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| Online Access: | Get full text |
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| Summary: | Oxalic acid-mediated conversion of alcohols to thiocyante and/or isothiocyanate is described. Aliphatic tertiary alcohols give isothiocyanate by the reaction with NaSCN in the presence of I2, whereas they give thiocyanate without it. |
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| ISSN: | 0366-7022 1348-0715 |