Room Temperature Synthesis and Crystal Structure of mer-[MoBr3Py3], the Vibrational Spectra ofmer-[MoBr3Py3], mer-[MoI3Py3] and trans,trans-[MoBr2Py4][MoBr4Py2]
The reaction of MoBr3 and pyridine at room temperature provided single crystals of mer-[MoX3Py3]. mer-[MoBr3Py3] crystallizes in P21/n monoclinic space group with cell dimensions a = 9.2297(5) Å, b = 12.911(8) Å, c = 15.7022(9) Å and [beta] = 90.479(3)°. There are four formula units in a unit cell....
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| Published in: | Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 639; no. 6; p. 939 |
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| Main Authors: | , , |
| Format: | Journal Article |
| Language: | English German |
| Published: |
Weinheim
Wiley Subscription Services, Inc
01-05-2013
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| Online Access: | Get full text |
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| Summary: | The reaction of MoBr3 and pyridine at room temperature provided single crystals of mer-[MoX3Py3]. mer-[MoBr3Py3] crystallizes in P21/n monoclinic space group with cell dimensions a = 9.2297(5) Å, b = 12.911(8) Å, c = 15.7022(9) Å and [beta] = 90.479(3)°. There are four formula units in a unit cell. Mo-N distances are in the range 2.196(8)-2.214(8) Å and Mo-Br distances are 2.573(1) Å and 2.574(1) Å. Fundamental vibrational frequencies of pyridine molecules are strongly affected upon coordination in all three coordination compounds: mer-[MoBr3Py3], mer-[MoI3Py3] and trans,trans-[MoBr2Py4][MoBr4Py2]. [PUBLICATION ABSTRACT] |
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| ISSN: | 0044-2313 1521-3749 |
| DOI: | 10.1002/zaac.201300122 |