Synthesis, characterization, thermal

• Published in: Arabian journal of chemistry Vol. 10; no. 6; pp. 761 - 768
• Main Authors: Selma Bal, Joseph Donald Connolly
• Format: Journal Article
• Language: English
• Published: Elsevier 01-09-2017
• Subjects: Azo-imine ligand; Catalysis; Complex; Thermal
• ISSN: 1878-5352
• DOI: 10.1016/j.arabjc.2015.11.012

This work explains the synthesis of a new azo-Schiff base compound, derived from condensation between N-ethylcarbazole-3-carbaldehyde and 1,3-diaminopropane, followed by azo coupling reaction with the diazonium salt of 2-amino-4-methyl phenol. The newly synthesized azo-Schiff base was further reacted with the acetate salts of Copper, Cobalt and Nickel to give three coordination compounds. All synthesized compounds have been characterized through spectral analysis. The coordination compounds have been examined for their thermal and catalytic features. Good and moderate yields were obtained for the oxidation of styrene and cyclohexene. Thermal features of the ligand and its complexes have been explained and the results obtained have supported the proposed structures.