Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by Cu(Ⅱ)-imine complex

A series of new ligands L_1-L_7 were readily prepared in one step.Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Cu(Ⅱ)-L complex has been developed.The remarkable advantages of this reaction are mild reaction conditions,simple workup procedure,high yields of products and...

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Bibliographic Details
Published in:中国化学快报:英文版 Vol. 22; no. 10; pp. 1155 - 1158
Main Author: Ning Ning Wan Yong Lei Yang Wen Ping Wang Zheng Feng Xie Ji De Wang
Format: Journal Article
Language:English
Published: 2011
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Summary:A series of new ligands L_1-L_7 were readily prepared in one step.Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Cu(Ⅱ)-L complex has been developed.The remarkable advantages of this reaction are mild reaction conditions,simple workup procedure,high yields of products and the use of ethanol as a green solvent.
Bibliography:Ning Ning Wan,Yong Lei Yang,Wen Ping Wang, Zheng Feng Xie,Ji De Wang a College of Chemistry and Chemical Engineering,Xinjiang University,Urumqi 830046,China b Key Laboratory of Oil & Gas Fine Chemicals of Ministry of Education,Xinjiang University,Urumqi 830046,China
11-2710/O6
Friedel-Crafts alkylation; Indole; Nitroalkene; Copper; Imine
A series of new ligands L_1-L_7 were readily prepared in one step.Friedel-Crafts alkylation of indoles with nitroalkenes catalyzed by a novel Cu(Ⅱ)-L complex has been developed.The remarkable advantages of this reaction are mild reaction conditions,simple workup procedure,high yields of products and the use of ethanol as a green solvent.
ISSN:1001-8417
1878-5964