Peculiarities of the microwave properties of hard–soft functional composites SrTb0.01Tm0.01Fe11.98O19–AFe2O4 (A = Co, Ni, Zn, Cu, or Mn)

• Published in: RSC advances Vol. 10; no. 54; pp. 32638 - 32651
• Main Authors: Trukhanov, A V, Algarou, N A, Slimani, Y, Almessiere, M A, Baykal, A, Tishkevich, D I, Vinnik, D A, Vakhitov, M G, Klygach, D S, Silibin, M V, Zubar, T I, Trukhanov, S V
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 03-09-2020; The Royal Society of Chemistry
• Subjects: Chemical composition; Chemistry; Cobalt; Composite materials; Copper; Dielectric loss; Dielectric properties; Dipoles; Electromagnetic absorption; Ferrites; Frequency ranges; Grain size; Investigations; Manganese; Microstructural analysis; Microstructure; Nickel; Polarization; Sol-gel processes; Spinel; Zinc
• ISSN: 2046-2069
• DOI: 10.1039/d0ra05087c

Herein, we investigated the correlation between the chemical composition, microstructure, and microwave properties of composites based on lightly Tb/Tm-doped Sr-hexaferrites (SrTb0.01Tm0.01Fe11.98O19) and spinel ferrites (AFe2O4, A = Co, Ni, Zn, Cu, or Mn), which were fabricated by a one-pot citrate sol–gel method. Powder XRD patterns of products confirmed the presence of pure hexaferrite and spinel phases. Microstructural analysis was performed based on SEM images. The average grain size for each phase in the prepared composites was calculated. Comprehensive investigations of dielectric properties (real (ϵ′) and imaginary parts (ϵ′′) of permittivity, dielectric loss tangent (tan(δ)), and AC conductivity) were performed in the 1–3 × 106 Hz frequency range at 20–120 °C. Frequency dependency of microwave properties were investigated using the coaxial method in frequency range of 2–18 GHz. The non-linear behavior of the main microwave properties with a change in composition may be due to the influence of the soft magnetic phase. It was found that Mn- and Ni-spinel ferrites achieved the strongest electromagnetic absorption. This may be due to differences in the structures of the electron shell and the radii of the A-site ions in the spinel phase. It was discovered that the ionic polarization transformed into the dipole polarization.