Semiconducting Transport in Pb10−XCux(PO4)6O Sintered from Pb2SO5 and Cu3P

• Published in: Advanced functional materials Vol. 33; no. 48
• Main Authors: Liu, Li, Meng, Ziang, Wang, Xiaoning, Chen, Hongyu, Duan, Zhiyuan, Zhou, Xiaorong, Yan, Han, Qin, Peixin, Liu, Zhiqi
• Format: Journal Article
• Language: English
• Published: Hoboken Wiley Subscription Services, Inc 23-11-2023
• Subjects: Apatite; Copper; Copper sulfides; Crystal structure; Crystallography; Cu3P; electrical transport properties; Magnetic levitation; Magnetic properties; Materials science; modified lead‐apatite; Pb2SO5; Permanent magnets; Phase distribution; Phosphides; purported superconductors; Room temperature; Sintering (powder metallurgy); Superconductivity; Transport phenomena
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.202308938

The recent claim on the discovery of ambient‐pressure room‐temperature superconductivity in Cu‐doped lead‐apatite has attracted sensational attention. The intriguing compound has been fabricated by sintering lanarkite (Pb2SO5) and copper(І) phosphide (Cu3P). To verify this exciting claim, Pb2SO5, Cu3P, and finally the modified lead‐apatite Pb10−xCux(PO4)6O have been successfully synthesized. Detailed electrical transport and magnetic properties of these compounds are systematically analyzed. It turns out that Pb2SO5 is a highly insulating diamagnet and Cu3P is a paramagnetic metal. The obtained nominal Pb10−xCux(PO4)6O compound sintered from Pb2SO5 and Cu3P exhibits semiconductor‐like transport behavior with a large room‐temperature resistivity of ≈1.94 × 104 Ω·cm, although the major phase of the compound shows consistent X‐ray diffraction spectrum with the previously reported structure data. In addition, when a Pb10−xCux(PO4)6O pellet pressed from uniformly ground powder is located on top of a commercial Nd2Fe14B magnet at room temperature, no repulsion can be felt and no magnetic levitation is observed either. The large difference in electrical and magnetic properties between the compounds and the previously reported compounds might be induced by distinct fine crystallographic structures, diverse multi‐phase distributions, and different concentrations of impurity phases such as Cu2S, all of which deserve further study.
The recent claim on the discovery of ambient‐pressure room‐temperature superconductivity has triggered sensational attention. In this work, Liu, Qin, and coworkers have successfully synthesized the nominal Cu‐doped lead‐apatite, which shows semiconducting transport behavior. The fine crystallographic structures, multiphase distributions, and impurity phases might have important effects on the physical properties of the resulting compound that is indeed a complex mixture.