Surface Modification of Nano‐Cu2O for Controlling CO2 Electrochemical Reduction to Ethylene and Syngas

• Published in: Angewandte Chemie International Edition Vol. 61; no. 11
• Main Authors: Luo, Haiqiang, Li, Bo, Ma, Jian‐Gong, Cheng, Peng
• Format: Journal Article
• Language: English
• Published: Weinheim Wiley Subscription Services, Inc 07-03-2022
• Edition: International ed. in English
• Subjects: Carbon dioxide; Catalysts; Chemical reduction; Copper oxides; ECO2RR; Electrochemistry; Electrolytes; Ethylene; Metal-organic frameworks; Nano-Cu2O; Reducing agents; Selectivity; Syngas; Synthesis gas
• ISSN: 1433-7851; 1521-3773
• DOI: 10.1002/anie.202116736

In the surroundings of carbon neutrality, nano‐Cu2O is considered a promising catalyst for the electrochemical CO2 reduction reaction (ECO2RR), whose improvements in product selectivity still require considerable efforts. Here, we present an efficient strategy for controlling the ECO2RR product by modifying the surface of nano‐Cu2O, i.e., by controlling the exposed facets via a reductant‐controlled method to achieve the highest C2H4 selectivity (Faradic efficiency=74.1 %) for Cu2O‐based catalysts in neutral electrolytes, and introducing a well‐suited metal–organic framework (MOF) coating on the surface of nano‐Cu2O to obtain syngas completely with an appropriate H2:CO ratio. Detailed mechanism and key intermediate have been illustrated by DFT calculations. Our systematic strategy is expected to control the ECO2RR product, improve the selectivity, and provide a reliable method for CO2 management and the green production of important carbon resources.
Electrochemical CO2 reduction reaction (ECO2RR) with controllable production of important carbon resources was achieved by a surface modification strategy of nano‐Cu2O catalysts. Through facet controlling the highest C2H4 selectivity among Cu2O‐based catalysts was achieved, while the products were completely converted to syngas with an appropriate H2:CO ratio via a MOF coating on the surface of the nano‐Cu2O.