Permanent magnet alloys based on Sm2Co17; phase evolution in the quinary system Sm-Zr-Fe-Co-Cu

In the five-component permanent magnets based on Sm2Co17 the formation of the familiar microstructural features (2:17 cell, 1:5 cell wall, and 1:3 lamellae) are elucidated with the help of recent and past information on the phase equilibria and crystal structures. Contrary to Zr-free alloys, in whic...

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Bibliographic Details
Published in:Zeitschrift für Metallkunde Vol. 96; no. 1; pp. 17 - 23
Main Authors: STADELMAIER, H. H, GOLL, D, KRONMüLLER, H
Format: Journal Article
Language:English
Published: München Hanser 2005
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Summary:In the five-component permanent magnets based on Sm2Co17 the formation of the familiar microstructural features (2:17 cell, 1:5 cell wall, and 1:3 lamellae) are elucidated with the help of recent and past information on the phase equilibria and crystal structures. Contrary to Zr-free alloys, in which the 1:5 cell-wall phase can form directly, the quinary alloys, to attain peak magnetic coercivity, undergo a transformation within the cell walls from undesirable 2:7 + 5:19 to high-anisotropy 1:5. A dramatic increase in the Cu content of the cell wall accompanies this transformation.
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ISSN:0044-3093
DOI:10.3139/146.018078