Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride

In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by i...

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Bibliographic Details
Published in:	Acta crystallographica. Section E, Structure reports online Vol. 66; no. Pt 11; p. m1353
Main Authors:	Cortes C, Laura, Burgos C, Ana E, Okio, Coco K Y A
Format:	Journal Article
Language:	English
Published:	United States International Union of Crystallography 02-10-2010
Subjects:	Metal-Organic Papers
Online Access:	Get full text
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Summary:	In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1600-5368
DOI:	10.1107/S1600536810038705