On the handedness of helical aggregates of C3 tricarboxamides: a multichiroptical characterization

On the handedness of helical aggregates of C3 tricarboxamides: a multichiroptical characterization

A complete chiroptical characterization of the supramolecular polymers formed by tricarboxamides and is performed using ECD, VCD and CPL dichroic techniques. The helical aggregates show an intense CPL signal and their absolute P- or M-configuration is assigned with the help of theoretical calculatio...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) Vol. 51; no. 48; p. 9781
Main Authors: Nieto-Ortega, Belén, García, Fátima, Longhi, Giovanna, Castiglioni, Ettore, Calbo, Joaquín, Abbate, Sergio, López Navarrete, Juan T, Ramírez, Francisco J, Ortí, Enrique, Sánchez, Luis, Casado, Juan
Format: Journal Article
Language:English
Published: England 18-06-2015
Subjects:
Amides - chemistry
Polymers - chemistry
Stereoisomerism
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Summary:A complete chiroptical characterization of the supramolecular polymers formed by tricarboxamides and is performed using ECD, VCD and CPL dichroic techniques. The helical aggregates show an intense CPL signal and their absolute P- or M-configuration is assigned with the help of theoretical calculations.
ISSN:1364-548X
DOI:10.1039/c5cc03054d