Harnessing Glycal-Epoxide Rearrangements: The Generation of the AB, EF, and IJ Rings of Adriatoxin

Harnessing Glycal-Epoxide Rearrangements: The Generation of the AB, EF, and IJ Rings of Adriatoxin

Die Leiter hoch: Der Aufbau dreier bicyclischer Untereinheiten von Adriatoxin gelang mithilfe von Glycal‐Epoxid‐ und Glycal‐Claisen‐Umlagerungen sowie C‐Glycosid bildenden Reaktionen.

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Bibliographic Details
Published in:Angewandte Chemie Vol. 120; no. 42; pp. 8175 - 8178
Main Authors: Osei Akoto, Clement, Rainier, Jon D.
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 06-10-2008
WILEY‐VCH Verlag
Subjects:
Enole
Epoxidierungen
Metathese
Titan
Umlagerungen
Online Access:Get full text
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Description
Summary:Die Leiter hoch: Der Aufbau dreier bicyclischer Untereinheiten von Adriatoxin gelang mithilfe von Glycal‐Epoxid‐ und Glycal‐Claisen‐Umlagerungen sowie C‐Glycosid bildenden Reaktionen.
Bibliography:We are grateful to the National Institutes of Health, General Medical Sciences (GM56677) for support of this work. C.O.A. acknowledges Pfizer for a graduate fellowship. We would like to thank the support staff at the University of Utah and especially Dr. Charles Mayne (NMR) and Dr. Jim Muller (MS) for their help in obtaining data.
ark:/67375/WNG-N1B25682-C
National Institutes of Health, General Medical Sciences - No. GM56677
ArticleID:ANGE200803791
istex:830066F4C425B1F71F392635E651E752EFB8BE44
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.200803791