Bis­[tris(1-methyl-1H-imidazol-2-yl)­phosphine-κ3N3]­iron(II) tetra­chloro­ferrate(II) methanol tetrasolvate (ca 153 K) and bis­[tris(1-methyl-1H-imidazol-2-yl)­methanol-κ3N3]­iron(III) bis­[tetra­chloro­ferrate(III)] chloride (redetermination, ca 153 K)

• Published in: Acta crystallographica. Section C, Crystal structure communications Vol. 60; no. 7; pp. m311 - m313
• Main Authors: Batten, Michael P., Canty, Allan J., Cavell, Kingsley J., Rüther, Thomas, Skelton, Brian W., White, Allan H.
• Format: Journal Article
• Language: English
• Published: 5 Abbey Square, Chester, Cheshire CH1 2HU, England Munksgaard International Publishers 01-07-2004
• ISSN: 0108-2701; 1600-5759
• DOI: 10.1107/S0108270104010868

The first of the title compounds, [Fe(C12H15N6P)2][FeCl4]·4CH4O, is the first homoleptic bis­(ligand)­iron(II) species reported for this phospho­rus bridgehead ligand; interestingly, the complex is isomorphous with its tris(1‐methyl‐1H‐imidazol‐2‐yl)­methanol counterpart, the second of the title compounds, [Fe(C13H16N6O)2][FeCl4]2Cl. In both compounds, the Fe atom of the cation lies on an inversion centre. The structure determinations presented here allow an interesting comparison of iron(II) and iron(III) species in similar coordination environments.