Adsorption of PAA on the α-Al2O3 Surface

• Published in: Journal of the American Ceramic Society Vol. 90; no. 6; pp. 1709 - 1716
• Main Authors: Chen, H. Y. T., Wei, W. C. J., Hsu, K. C., Chen, C. S.
• Format: Journal Article
• Language: English
• Published: Malden, USA Blackwell Publishing Inc 01-06-2007; Blackwell
• Subjects: Applied sciences; Condensed matter: structure, mechanical and thermal properties; Exact sciences and technology; Physical properties; Physics; Polymer industry, paints, wood; Properties and testing; Solid surfaces and solid-solid interfaces; Surface properties; Surface structure and topography; Surfaces and interfaces; thin films and whiskers (structure and nonelectronic properties); Technology of polymers; Aluminium oxide; Adsorption; Computer simulation; Steric effect; Acrylic acid polymer; Empirical method; Adsorption structure; pH; Conformational changes; Chromatography; Gel permeation chromatography
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/j.1551-2916.2007.01644.x

The specific system of interest is the polyacrylic acid (PAA) and (0001) α‐Al2O3 surface, which was modeled and simulated by Cerius2 4.9 software with empirical potentials. The simulation predicted that the adsorbed conformations of PAA with a molecular weight (Mw) of 5000 were train and tail at pH <4 and >10, respectively. After gradually inserting additional PAA molecular chains, the adsorption reached a saturated amount. Gel permeation chromatography experimental results showed that the adsorption amount at pH 3.6 was three times greater than that at pH 11. Based on the results from simulations and experiments, a successively increasing pH environment was modeled to illustrate the possibility of optimizing electro‐steric effects by combining the higher adsorption density at a lower pH and strong steric repulsion of tail‐adsorbed configuration at a higher pH.