A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure
No pressure: A simple monomeric tungstate, [WO4]2−, serves as a highly efficient homogeneous catalyst for various transformations of CO2 at atmospheric pressure. The tungsten‐oxo moiety activates CO2 and the substrate simultaneously. The catalyst system is high yielding and applicable to a wide rang...
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| Published in: | Angewandte Chemie International Edition Vol. 51; no. 27; pp. 6700 - 6703 |
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| Abstract | No pressure: A simple monomeric tungstate, [WO4]2−, serves as a highly efficient homogeneous catalyst for various transformations of CO2 at atmospheric pressure. The tungsten‐oxo moiety activates CO2 and the substrate simultaneously. The catalyst system is high yielding and applicable to a wide range of substrates such as amines (see scheme), 2‐aminobenzonitriles, and propargylic alcohols. |
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| AbstractList | No pressure: A simple monomeric tungstate, [WO4]2−, serves as a highly efficient homogeneous catalyst for various transformations of CO2 at atmospheric pressure. The tungsten‐oxo moiety activates CO2 and the substrate simultaneously. The catalyst system is high yielding and applicable to a wide range of substrates such as amines (see scheme), 2‐aminobenzonitriles, and propargylic alcohols. |
| Author | Kimura, Toshihiro Kamata, Keigo Mizuno, Noritaka |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22674893$$D View this record in MEDLINE/PubMed |
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| Copyright | Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Notes | This work was supported in part by the Japan Society for the Promotion of Science (JSPS) through its "Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program), and a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan. ArticleID:ANIE201203189 Japan Society for the Promotion of Science (JSPS) istex:08F5F8FB001B85C7A1F4545205C828BF61C368AF ark:/67375/WNG-R981HWGF-S Ministry of Education, Culture, Science, Sports, and Technology of Japan This work was supported in part by the Japan Society for the Promotion of Science (JSPS) through its “Funding Program for World‐Leading Innovative R&D on Science and Technology (FIRST Program), and a Grant‐in‐Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
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| SubjectTerms | carbon dioxide fixation heterocycles homogeneous catalysis reaction mechanism tungstate |
| Title | A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure |
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