A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure

A Bifunctional Tungstate Catalyst for Chemical Fixation of CO2 at Atmospheric Pressure

No pressure: A simple monomeric tungstate, [WO4]2−, serves as a highly efficient homogeneous catalyst for various transformations of CO2 at atmospheric pressure. The tungsten‐oxo moiety activates CO2 and the substrate simultaneously. The catalyst system is high yielding and applicable to a wide rang...

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Bibliographic Details
Published in:Angewandte Chemie International Edition Vol. 51; no. 27; pp. 6700 - 6703
Main Authors: Kimura, Toshihiro, Kamata, Keigo, Mizuno, Noritaka
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 02-07-2012
WILEY‐VCH Verlag
Subjects:
carbon dioxide fixation
heterocycles
homogeneous catalysis
reaction mechanism
tungstate
Online Access:Get full text
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Summary:No pressure: A simple monomeric tungstate, [WO4]2−, serves as a highly efficient homogeneous catalyst for various transformations of CO2 at atmospheric pressure. The tungsten‐oxo moiety activates CO2 and the substrate simultaneously. The catalyst system is high yielding and applicable to a wide range of substrates such as amines (see scheme), 2‐aminobenzonitriles, and propargylic alcohols.
Bibliography:This work was supported in part by the Japan Society for the Promotion of Science (JSPS) through its "Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program), and a Grant-in-Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan.
ArticleID:ANIE201203189
Japan Society for the Promotion of Science (JSPS)
istex:08F5F8FB001B85C7A1F4545205C828BF61C368AF
ark:/67375/WNG-R981HWGF-S
Ministry of Education, Culture, Science, Sports, and Technology of Japan
This work was supported in part by the Japan Society for the Promotion of Science (JSPS) through its “Funding Program for World‐Leading Innovative R&D on Science and Technology (FIRST Program), and a Grant‐in‐Aid for Scientific Research from the Ministry of Education, Culture, Science, Sports, and Technology of Japan.
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201203189