Photoluminescent CaCu3Ti4O12-Based Thin Films Synthesized by a Sol-Gel Method

• Published in: Journal of the American Ceramic Society Vol. 91; no. 12; pp. 4162 - 4164
• Main Authors: Parra, Rodrigo, Joanni, Ednan, Espinosa, José W. M., Tararam, Ronald, Cilense, Mário, Bueno, Paulo R., Varela, Jose A., Longo, Elson
• Format: Journal Article
• Language: English
• Published: Malden, USA Blackwell Publishing Inc 01-12-2008; Wiley
• Subjects: Condensed matter: electronic structure, electrical, magnetic, and optical properties; Exact sciences and technology; Insulators; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of specific thin films; Physics; Thin films; Atomic force microscopy; Particle size; Photoluminescence; Calcium Copper Titanates Mixed; Microstructure; Sol-gel process; Heat treatments
• ISSN: 0002-7820; 1551-2916
• DOI: 10.1111/j.1551-2916.2008.02817.x

Results on the characterization of photoluminescent CaCu3Ti4O12‐based films, prepared from a sol–gel precursor and heat treated at 700°C, are reported for the first time. The samples showed two emission bands at 554 and 800 nm when excited with a 488 nm Ar‐ion laser. The photoluminescent emission measured at room temperature in thin films was attributed to complex vacancy clusters. The films consisted of CaCu3Ti4O12 with traces of TiO2, CuO, and CaTiO3 and showed porous structures with an average particle size of 50 nm under atomic force microscopy resolution.