Organotin(IV) chloride complexes with phosphocholine and dimyristoyl-L-α-phosphatidylcholine

Organotin(IV) chloride complexes with phosphocholine and dimyristoyl-L-α-phosphatidylcholine

Several complexes of R nSnCl4−n (R = Me, Ph, n= 1–3; R = nBu, n = 2, 3) with phosphocholine and dimyristoyl‐L‐α‐phosphatidylcholine (phospholipid) have been synthesized and characterized by means of Mössbauer spectroscopy and NMR. Triorganotin chlorides form complexes of (R3SnCl)2·L stoichiometry wi...

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Bibliographic Details
Published in:Applied organometallic chemistry Vol. 14; no. 8; pp. 443 - 448
Main Authors: Grigoriev, E. V., Pellerito, L., Yashina, N. S., Pellerito, C., Petrosyan, V. S.
Format: Journal Article
Language:English
Published: Chichester, UK John Wiley & Sons, Ltd 01-08-2000
Subjects:
Mössbauer spectroscopy
NMR
organotin chlorides
phosphocholine
phospholipid
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Summary:Several complexes of R nSnCl4−n (R = Me, Ph, n= 1–3; R = nBu, n = 2, 3) with phosphocholine and dimyristoyl‐L‐α‐phosphatidylcholine (phospholipid) have been synthesized and characterized by means of Mössbauer spectroscopy and NMR. Triorganotin chlorides form complexes of (R3SnCl)2·L stoichiometry with a trigonal bipyramidal pentacoordinate tin environment, while the others form 1:1 complexes with an octahedral hexacoordinate tin environment, with the ligands coordinating through anionic phosphodiester moieties in all cases. Copyright © 2000 John Wiley & Sons, Ltd.
Bibliography:ark:/67375/WNG-1R1D35X0-9
istex:CD4A865294F4662C72741FFA2E89FBC2434346AF
ArticleID:AOC997
ISSN:0268-2605
1099-0739
DOI:10.1002/1099-0739(200008)14:8<443::AID-AOC997>3.0.CO;2-4