AISI 304 L stainless steel decontamination by a corrosion process using cerium IV regenerated by ozone. Part I: Study of the accelerated corrosion process

• Published in: Journal of applied electrochemistry Vol. 33; no. 8; pp. 703 - 708
• Main Authors: CAIRE, J. P, LAURENT, F, CULLIE, S, DALARD, F, FULCONIS, J. M, DELAGRANGE, H
• Format: Journal Article
• Language: English
• Published: Heidelberg Springer 01-08-2003; Springer Verlag
• Subjects: Applied sciences; Chemical Sciences; Cleaning. Degreasing. Pickling; Exact sciences and technology; Material chemistry; Metals. Metallurgy; Production techniques; Surface treatment; Surface cleaning; Cerium Nitrates; cerium; stainless steel; Ozone; Nitric acid; Acidic solution; Surface treatment; Metal scrap; Corrosion; Decontamination; Medium effect; Stainless steel-304L; corrosion; decontamination; ozone
• ISSN: 0021-891X; 1572-8838
• DOI: 10.1023/A:1025051306270

This paper describes the study of a new decontamination process of AISI 304L stainless steel from dismantled nuclear power plants. A very thin active contaminated surface layer was stripped from the underlying metal by corrosion in a solution of nitric acid with the addition of cerium nitrate. The Ce4+/Ce3+ concentration ratio was initially equal to unity and ozone/oxygen bubbles were used to regenerate Ce3+ ions into Ce4+ ions. The study was performed in a laboratory cell prior to preliminary optimization in a three-litre reactor. The objective was to obtain a corrosion rate of about 10 micrometers per day. This target was reached in 10–2 mol l–1 of cerium nitrate with bubbling of a 1.56 g h–1 ozone flow in a 60 l h–1 total gas flow. The corrosion rate depended essentially on the Ce4+ concentration. The stainless steel exhibited intergranular corrosion. The corrosion rate was monitored by measuring the solution oxidizing potential using a precious metal electrode.