Effects of magnetic anisotropy and exchange in [Tm.sub.2][Fe.sub.17]

• Published in: Journal of experimental and theoretical physics Vol. 115; no. 5; pp. 837 - 1673
• Main Authors: Pirogov, A.N, Bogdanov, S.G, Rosenfeld, E.V, Park, J.-G, Choi, Y.N, Lee, Seongsu, Prokes, K, Golosova, N.O, Sashin, I.L, Kudrevatykh, N.V, Skryabin, Yu. N, Vokhmyanin, A.P
• Format: Journal Article
• Language: English
• Published: Springer 01-11-2012
• Subjects: Analysis; Anisotropy; Magnetization; Toy industry
• ISSN: 1063-7761; 1090-6509
• DOI: 10.1134/S106377611210010X

Neutron diffraction experiments have been carried out to study the magnetocrystalline anisotropy of two (2b and 2d) Tm sublattices and four (4f, 6g, 12j, and 12k) Fe sublattices in ferrimagnetic compound [Tm.sub.2][Fe.sub.17] (space group [P6.sub.3]/mmc). We have determined the temperature dependence of the magnitude and orientation of magnetization for each of the thulium and iron sublattices in the range (10-300) K. A spontaneous rotation (at about 90 K) of the Tm and Fe sublattice magnetizations from the c-axis to the basal plane is accompanied by a drastic change in the magnetization magnitude, signifying a large magnetization anisotropy. Both Tm sublattices exhibit an easy-axis type of the magnetocrystalline anisotropy. The Fe sublattices manifest both the uniaxial and planar anisotropy types. The sublattice formed by Fe atoms at the 4f position reveals the largest planar anisotropy constant. The Fe atoms at the 4f position show a uniaxial anisotropy. We find that the inelastic neutron scattering spectra measured below and above the spin-reorientation transition are remarkably different.