Development of Imino-[lambda]3-iodanes with Improved Reactivity for Metal-Free [2+2+1] Cycloaddition-Type Reactions

Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles.

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Bibliographic Details
Published in:	Advanced synthesis & catalysis Vol. 359; no. 21; p. 3860
Main Authors:	Baba, Takafumi, Takahashi, Shunsuke, Kambara, Yui, Yoshimura, Akira, Nemykin, Victor N, Zhdankin, Viktor V, Saito, Akio
Format:	Journal Article
Language:	English
Published:	Heidelberg Wiley Subscription Services, Inc 01-11-2017
Subjects:	Cycloaddition
Online Access:	Get full text
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Description
Summary:	Aiming at the enhancement of electrophilicity of imino-λ3-iodanes, we have developed (tosylimino)pentafluorophenyl-λ3-iodane, which shows superior reactivity compared to the commonly used (tosylimino)phenyl-λ3-iodane in the [2+2+1]-type synthesis of imidazoles.
ISSN:	1615-4150 1615-4169
DOI:	10.1002/adsc.201700934