Structural and morphology of ZnO nanorods synthesized using ZnO seeded growth hydrothermal method and its properties as UV sensing

• Published in: PloS one Vol. 7; no. 11; p. e50405
• Main Authors: Ridhuan, Nur Syafinaz, Razak, Khairunisak Abdul, Lockman, Zainovia, Abdul Aziz, Azlan
• Format: Journal Article
• Language: English
• Published: United States Public Library of Science 26-11-2012; Public Library of Science (PLoS)
• Subjects: Analysis; Annealing; Chemical synthesis; Chemistry; Depth indicators; Detection; Emission; Emissions; Heat; Heat treatment; Hydrogen-Ion Concentration; Materials Science; Methods; Mineral resources; Morphology; Nanorods; Nanotubes - chemistry; Nanotubes - ultrastructure; Nitrates; Nitrates - chemistry; Optical properties; Organic chemicals; Oxidation; pH effects; Photovoltaic cells; Preferred orientation; Reaction time; Seeds; Silicon substrates; Solutions - chemistry; Spectrum Analysis, Raman; Surface Properties; Temperature; Thin films; U.V. radiation; Ultraviolet radiation; Ultraviolet Rays; X-Ray Diffraction; Zinc; Zinc Compounds - chemistry; Zinc oxide; Zinc Oxide - chemistry; Zinc oxides; Penang Malaysia; Malaysia
• ISSN: 1932-6203; 1932-6203
• DOI: 10.1371/journal.pone.0050405

In this study, zinc oxide (ZnO) nanorod arrays were synthesized using a simple hydrothermal reaction on ZnO seeds/n-silicon substrate. Several parameters were studied, including the heat-treatment temperature to produce ZnO seeds, zinc nitrate concentration, pH of hydrothermal reaction solution, and hydrothermal reaction time. The optimum heat-treatment temperature to produce uniform nanosized ZnO seeds was 400°C. The nanorod dimensions depended on the hydrothermal reaction parameters. The optimum hydrothermal reaction parameters to produce blunt tip-like nanorods (770 nm long and 80 nm in top diameter) were 0.1 M zinc nitrate, pH 7, and 4 h of growth duration. Phase analysis studies showed that all ZnO nanorods exhibited a strong (002) peak. Thus, the ZnO nanorods grew in a c-axis preferred orientation. A strong ultraviolet (UV) emission peak was observed for ZnO nanorods grown under optimized parameters with a low, deep-level emission peak, which indicated high optical property and crystallinity of the nanorods. The produced ZnO nanorods were also tested for their UV-sensing properties. All samples responded to UV light but with different sensing characteristics. Such different responses could be attributed to the high surface-to-volume ratio of the nanorods that correlated with the final ZnO nanorods morphology formed at different synthesis parameters. The sample grown using optimum synthesis parameters showed the highest responsivity of 0.024 A/W for UV light at 375 nm under a 3 V bias.