A Highly Efficient Chemiluminescence System Based on an Enhancing Effect of Ag Nanoclusters/Graphene Quantum Dots Mixture for Ultrasensitive Detection of Rabeprazole
Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO3 and...
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Published in: | Analytical Sciences Vol. 35; no. 4; pp. 385 - 391 |
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The Japan Society for Analytical Chemistry
2019
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Abstract | Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO3 and a thermal treatment of glucose, respectively. After the characterization steps, the beneficial behavior of the prepared nanomaterial was investigated in CL systems. The oxidation reaction of KMnO4-rhodamine B produced weak CL emission. However, the presence of AgNCs and GQDs led to a synergetic enhancing effect, and thus higher emission was obtained. A possible mechanism was investigated for this effect using absorption and fluorescence experiments. Furthermore, rabeprazole showed a relatively selective enhancing impact on the CL emission. The CL intensity was linearly increased in the rabeprazole concentration range of 4 – 133 ng mL−1 with a detection limit (3Sb/m) of 1.1 ng mL−1. The developed CL method was utilized for the measurement of Rbp in biological samples with acceptable precision and accuracy. |
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AbstractList | Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO3 and a thermal treatment of glucose, respectively. After the characterization steps, the beneficial behavior of the prepared nanomaterial was investigated in CL systems. The oxidation reaction of KMnO4-rhodamine B produced weak CL emission. However, the presence of AgNCs and GQDs led to a synergetic enhancing effect, and thus higher emission was obtained. A possible mechanism was investigated for this effect using absorption and fluorescence experiments. Furthermore, rabeprazole showed a relatively selective enhancing impact on the CL emission. The CL intensity was linearly increased in the rabeprazole concentration range of 4 – 133 ng mL−1 with a detection limit (3Sb/m) of 1.1 ng mL−1. The developed CL method was utilized for the measurement of Rbp in biological samples with acceptable precision and accuracy. Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO 3 and a thermal treatment of glucose, respectively. After the characterization steps, the beneficial behavior of the prepared nanomaterial was investigated in CL systems. The oxidation reaction of KMnO 4 -rhodamine B produced weak CL emission. However, the presence of AgNCs and GQDs led to a synergetic enhancing effect, and thus higher emission was obtained. A possible mechanism was investigated for this effect using absorption and fluorescence experiments. Furthermore, rabeprazole showed a relatively selective enhancing impact on the CL emission. The CL intensity was linearly increased in the rabeprazole concentration range of 4–133 ng mL −1 with a detection limit (3 S b / m ) of 1.1 ng mL −1 . The developed CL method was utilized for the measurement of Rbp in biological samples with acceptable precision and accuracy. Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO3 and a thermal treatment of glucose, respectively. After the characterization steps, the beneficial behavior of the prepared nanomaterial was investigated in CL systems. The oxidation reaction of KMnO4-rhodamine B produced weak CL emission. However, the presence of AgNCs and GQDs led to a synergetic enhancing effect, and thus higher emission was obtained. A possible mechanism was investigated for this effect using absorption and fluorescence experiments. Furthermore, rabeprazole showed a relatively selective enhancing impact on the CL emission. The CL intensity was linearly increased in the rabeprazole concentration range of 4 - 133 ng mL-1 with a detection limit (3Sb/m) of 1.1 ng mL-1. The developed CL method was utilized for the measurement of Rbp in biological samples with acceptable precision and accuracy. Herein, an efficient chemiluminescence (CL) reaction with a high emission intensity is reported based on a synergistic improving effect of silver nanoclusters (AgNCs) and graphene quantum dots (GQDs). First, the syntheses of AgNCs and GQDs were simply performed by the chemical reducing of AgNO and a thermal treatment of glucose, respectively. After the characterization steps, the beneficial behavior of the prepared nanomaterial was investigated in CL systems. The oxidation reaction of KMnO -rhodamine B produced weak CL emission. However, the presence of AgNCs and GQDs led to a synergetic enhancing effect, and thus higher emission was obtained. A possible mechanism was investigated for this effect using absorption and fluorescence experiments. Furthermore, rabeprazole showed a relatively selective enhancing impact on the CL emission. The CL intensity was linearly increased in the rabeprazole concentration range of 4 - 133 ng mL with a detection limit (3S /m) of 1.1 ng mL . The developed CL method was utilized for the measurement of Rbp in biological samples with acceptable precision and accuracy. |
Author | HASSANZADEH, Javad ABOLHASANI, Jafar YOUSEFZADEH, Ashraf SOMI, Mohammad Hossein |
Author_xml | – sequence: 1 fullname: YOUSEFZADEH, Ashraf organization: Department of Chemistry, Tabriz Branch, Islamic Azad University – sequence: 2 fullname: ABOLHASANI, Jafar organization: Department of Chemistry, Tabriz Branch, Islamic Azad University – sequence: 3 fullname: HASSANZADEH, Javad organization: Research Laboratory of Advanced Water and Wastewater Treatment Processes, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz – sequence: 4 fullname: SOMI, Mohammad Hossein organization: Liver and Gastrointestinal Diseases Research Center, Tabriz University of Medical Sciences |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30971635$$D View this record in MEDLINE/PubMed |
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Cites_doi | 10.12973/ejac.2017.00169a 10.1016/j.saa.2014.10.018 10.2116/analsci.32.317 10.1039/c1jm11452b 10.1002/jssc.201601232 10.1039/C8TC01966E 10.1016/j.apt.2017.11.028 10.1007/s10853-013-7906-4 10.2116/analsci.18P412 10.1142/9789813202504_0002 10.1365/s10337-007-0428-y 10.1016/j.trac.2016.07.002 10.1021/acs.jpcc.7b04870 10.1016/j.trac.2015.08.018 10.1016/j.talanta.2017.08.107 10.1007/s40005-018-0387-3 10.2116/analsci.27.297 10.1007/s12272-017-0896-z 10.1016/j.jchromb.2015.01.023 10.1016/j.trac.2015.03.020 10.1016/j.aca.2013.11.016 10.1016/j.trac.2010.11.008 10.1016/j.saa.2013.01.068 10.1007/s11468-009-9088-0 10.1016/j.saa.2007.05.048 10.1016/j.flm.2017.12.006 10.2116/analsci.17.975 10.1080/05704928.2013.819514 10.1016/j.trac.2014.02.011 10.1002/asia.201700814 10.1039/C5CS00607D 10.1016/j.talanta.2017.01.066 10.2116/analsci.30.495 10.1016/j.jchromb.2005.07.027 10.1016/j.jchromb.2004.11.032 10.2116/analsci.34.131 10.1002/adma.200904199 10.1016/j.ijpharm.2007.08.035 10.1016/j.jpba.2005.12.016 |
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SubjectTerms | Ag nanoclusters amplifying effect Analytical Chemistry Biological properties Biological samples Chemiluminescence Chemistry Emission analysis Fluorescence Graphene graphene quantum dots Graphite - chemistry Heat treatment Luminescent Measurements Metal Nanoparticles - chemistry Nanoclusters Nanomaterials Organic chemistry Oxidation Particle Size Potassium permanganate Quantum dots Quantum Dots - chemistry rabeprazole Rabeprazole - analysis Rhodamine Silver Silver - chemistry Surface Properties |
Title | A Highly Efficient Chemiluminescence System Based on an Enhancing Effect of Ag Nanoclusters/Graphene Quantum Dots Mixture for Ultrasensitive Detection of Rabeprazole |
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