Dynamic metal-ligand coordination for multicolour and water-jet rewritable paper

• Published in: Nature communications Vol. 9; no. 1; p. 3
• Main Authors: Ma, Yun, She, Pengfei, Zhang, Kenneth Yin, Yang, Huiran, Qin, Yanyan, Xu, Zihan, Liu, Shujuan, Zhao, Qiang, Huang, Wei
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 09-01-2018; Nature Publishing Group; Nature Portfolio
• Subjects: 140/131; 140/58; 639/301/1005/1008; 639/638/263; 639/638/298/398; 639/638/911; Coordination compounds; Energy conservation; Forest conservation; Forest management; Humanities and Social Sciences; Jet printing; Ligands; Metals; multidisciplinary; Pollution control; Printing; Salts; Science; Science (multidisciplinary); Sustainability; Water pollution
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-017-02452-w

Rewritable paper has recently become prevalent in both academic research and marketplace due to the potential environmental advantages, including forest conservation, pollution reduction, energy saving and resource sustainability. However, its real-life applications are limited by a lack of effective strategy to realize multicolour and water-jet printing on rewritable paper with long legible image-lasting times. Herein, we report an effective strategy to construct rewritable paper based on colour or luminescence switching induced by dynamic metal–ligand coordination. This type of rewritable paper can be conveniently utilized for multicolour water-jet printing by using aqueous solutions containing different metal salts as ink. In addition, the printed images on the water-jet rewritable paper can be retained for a long time (> 6 months), which shows great progress compared to previous work. We believe that this type of rewritable paper could be considered as a prototype for multicolour water-jet printing to meet the practical needs.
Rewritable paper is environmentally favourable, but its practical realization is stifled by limited ink colour versatility and poor image retention times. Here, the authors exploit the relatively stable but reversible nature of metal–organic coordination bonds to produce long-lasting and multicoloured inks for rewritable paper.