Templated growth of oriented layered hybrid perovskites on 3D-like perovskites

• Published in: Nature communications Vol. 11; no. 1; p. 582
• Main Authors: Wang, Jifei, Luo, Shiqiang, Lin, Yun, Chen, Yifu, Deng, Yehao, Li, Zhimin, Meng, Ke, Chen, Gang, Huang, Tiantian, Xiao, Si, Huang, Han, Zhou, Conghua, Ding, Liming, He, Jun, Huang, Jinsong, Yuan, Yongbo
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 29-01-2020; Nature Publishing Group; Nature Portfolio
• Subjects: 140/146; 147/135; 147/136; 639/4077/909/4101/4096/946; 639/766/119/544; Ammonium; Charge transport; Crystal structure; Crystals; Drying; Humanities and Social Sciences; Liquid surfaces; multidisciplinary; Nucleation; Orientation; Perovskites; Photovoltaic cells; Salts; Science; Science (multidisciplinary); Solar cells; Spin coating; Thermodynamic equilibrium; Transport phenomena
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-019-13856-1

The manipulation of crystal orientation from the thermodynamic equilibrium states is desired in layered hybrid perovskite films to direct charge transport and enhance the perovskite devices performance. Here we report a templated growth mechanism of layered perovskites from 3D-like perovskites which can be a general design rule to align layered perovskites along the out-of-plane direction in films made by both spin-coating and scalable blading process. The method involves suppressing the nucleation of both layered and 3D perovskites inside the perovskite solution using additional ammonium halide salts, which forces the film formation starts from solution surface. The fast drying of solvent at liquid surface leaves 3D-like perovskites which surprisingly templates the growth of layered perovskites, enabled by the periodic corner-sharing octahedra networks on the surface of 3D-like perovskites. This discovery provides deep insights into the nucleation behavior of octahedra-array-based perovskite materials, representing a general strategy to manipulate the orientation of layered perovskites.
The orientation of layered perovskites plays a crucial role in their charge transport behavior and hence, the efficiency of related solar cells. Here, the authors find that preformed 3D-like perovskites can efficiently template the growth of layered perovskites and determine their orientation.