Tailoring exciton and excimer emission in an exfoliated ultrathin 2D metal-organic framework

• Published in: Nature communications Vol. 9; no. 1; pp. 2401 - 9
• Main Authors: Liao, Wei-Ming, Zhang, Jian-Hua, Yin, Shao-Yun, Lin, He, Zhang, Xingmin, Wang, Jihong, Wang, Hai-Ping, Wu, Kai, Wang, Zheng, Fan, Ya-Nan, Pan, Mei, Su, Cheng-Yong
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 19-06-2018; Nature Publishing Group; Nature Portfolio
• Subjects: 639/624/399; 639/638/298/398; 639/638/298/921; Calcium; Emission; Emissions; Excimers; Excitation; Excitons; Exfoliation; Genetic transformation; Humanities and Social Sciences; Interlayers; Metal-organic frameworks; Molecular chains; Morphology; multidisciplinary; Optical memory (data storage); Science; Science (multidisciplinary); Two dimensional models; Ultrasound; Van der Waals forces
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-018-04833-1

Two-dimensional (2D) metal–organic frameworks have exhibited a range of fascinating attributes, of interest to numerous fields. Here, a calcium-based metal-organic framework with a 2D layered structure has been designed. Dual emissions relating to intralayer excimers and interlayer trapped excitons are produced, showing excitation-dependent shifting tendency, characteristic of a low dimensional semiconductor nature. Furthermore, the layer stacking by weak van der Waals forces among dynamically coordinated DMF molecules enables exfoliation and morphology transformation, which can be achieved by ultrasound in different ratios of DMF/H
2
O solvents, or grinding under appropriate humidity conditions, leading to nano samples including ultrathin nanosheets with single or few coordination layers. The cutting down of layer numbers engenders suppression of interlayer exciton-related emission, resulting in modulation of the overall emitting color and optical memory states. This provides a rare prototypical model with switchable dual-channel emissions based on 2D-MOFs, in which the interlayer excitation channel can be reversibly tuned on/off by top-down exfoliation and morphology transformation.
Two dimensional (2D) metal-organic frameworks have demonstrated unique photophysical properties compared to their bulk analogs. Here, the authors demonstrate that exfoliation of 2D MOFs can suppress interlayer exciton-related emission, allowing for modulation of the overall emission color and switching of optical memory states.