Stress enhancement in the delayed yielding of colloidal gels

Networks of aggregated colloidal particles are solidlike and can sustain an applied shear stress while exhibiting little or no creep; however, ultimately they will catastrophically fail. We show that the time delay for this yielding decreases in two distinct exponential regimes with applied stress....

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Bibliographic Details
Published in:Physical review letters Vol. 106; no. 24; p. 248303
Main Authors: Sprakel, Joris, Lindström, Stefan B, Kodger, Thomas E, Weitz, David A
Format: Journal Article
Language:English
Published: United States 17-06-2011
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Summary:Networks of aggregated colloidal particles are solidlike and can sustain an applied shear stress while exhibiting little or no creep; however, ultimately they will catastrophically fail. We show that the time delay for this yielding decreases in two distinct exponential regimes with applied stress. This behavior is universal and found for a variety of colloidal gel systems. We present a bond-rupture model that quantitatively describes this behavior and highlights the role of mesoscopic structures. Our result gives new insight into the nature of yielding in these soft solid materials.
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ISSN:0031-9007
1079-7114
1079-7114
DOI:10.1103/physrevlett.106.248303