Determination of selected organophosphate esters in the aquatic environment of Austria

• Published in: The Science of the total environment Vol. 388; no. 1; pp. 290 - 299
• Main Authors: Martínez-Carballo, Elena, González-Barreiro, Carmen, Sitka, Andrea, Scharf, Sigrid, Gans, Oliver
• Format: Journal Article
• Language: English
• Published: Shannon Elsevier B.V 15-12-2007; Elsevier Science
• Subjects: Applied sciences; Austria; Chromatography, High Pressure Liquid; Continental surface waters; Earth sciences; Earth, ocean, space; Effluent water; Engineering and environment geology. Geothermics; Environmental Monitoring; Exact sciences and technology; Flame Retardants - analysis; Freshwater; Geologic Sediments - analysis; Liquid chromatography–tandem mass spectrometry; Natural water pollution; Organophosphate esters; Organophosphates - analysis; Organophosphorus flame retardants; Plasticizers; Plasticizers - analysis; Pollution; Pollution, environment geology; Reproducibility of Results; Rivers - chemistry; Sediment; Spectrometry, Mass, Electrospray Ionization; Surface water; Waste Disposal, Fluid; Wastewaters; Water Pollutants, Chemical - analysis; Water treatment and pollution; Austria; Europe; Plasticizers; Sediment; Organophosphorus flame retardants; Surface water; Liquid chromatography–tandem mass spectrometry; Organophosphate esters; Effluent water; Liquid liquid extraction; Flame retardant; Liquid chromatography-tandem mass spectrometry; Liquid chromatography; Solvent extraction; Sediments; Persistent organic pollutant; Ester; Plasticizer; Mass spectrometry MS/MS; Organic phosphate; Poison; Water pollution; Waste water discharge; Ultrasound; Organic compounds; Concentration distribution
• ISSN: 0048-9697; 1879-1026
• DOI: 10.1016/j.scitotenv.2007.08.005

Organophosphate esters are used in multitude of applications such as flame retardants, plasticizers and lubricants. In recent years concerns have been raised in regards to the environmental impact of some of the more commonly used phosphoric acid triesters, because many of them are toxic and persistent. Liquid–liquid extraction and ultrasound-assisted solvent extraction followed by liquid chromatography coupled to tandem mass spectrometry detection (LC−MS/MS) were used for the determination of nine priority organophosphate esters in waste and surface water, as well as in sediment samples for first time in Austria. Recoveries ranged from 63% to 94% in water and from 74 to 104% in sediment with estimated quantification limits between 2.6 and 7.9 ng/l in surface water, 4.1 and 13 ng/l in effluent waste water, and between 0.48 and 11 μg/kg in sediment. The validated method was applied to determine the occurrence of the selected organophosphorus flame retardants (OPFRs) and plasticizers in the aquatic environment of Austria. The impact of the discharge of waste water treatment plants into the receiving water bodies was also studied.