A metal-free electrocatalyst for carbon dioxide reduction to multi-carbon hydrocarbons and oxygenates

• Published in: Nature communications Vol. 7; no. 1; pp. 13869 - 6
• Main Authors: Wu, Jingjie, Ma, Sichao, Sun, Jing, Gold, Jake I., Tiwary, ChandraSekhar, Kim, Byoungsu, Zhu, Lingyang, Chopra, Nitin, Odeh, Ihab N., Vajtai, Robert, Yu, Aaron Z., Luo, Raymond, Lou, Jun, Ding, Guqiao, Kenis, Paul J. A., Ajayan, Pulickel M.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 13-12-2016; Nature Publishing Group; Nature Portfolio
• Subjects: 140/131; 140/133; 140/146; 639/301/299/886; 639/925/357/1017; Carbon dioxide; Carbon monoxide; Copper; Electrons; Graphene; Humanities and Social Sciences; Hydrocarbons; Morphology; multidisciplinary; Nanoparticles; Quantum dots; Science; Science (multidisciplinary); United States > US; Texas; Illinois
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/ncomms13869

Electroreduction of carbon dioxide into higher-energy liquid fuels and chemicals is a promising but challenging renewable energy conversion technology. Among the electrocatalysts screened so far for carbon dioxide reduction, which includes metals, alloys, organometallics, layered materials and carbon nanostructures, only copper exhibits selectivity towards formation of hydrocarbons and multi-carbon oxygenates at fairly high efficiencies, whereas most others favour production of carbon monoxide or formate. Here we report that nanometre-size N-doped graphene quantum dots (NGQDs) catalyse the electrochemical reduction of carbon dioxide into multi-carbon hydrocarbons and oxygenates at high Faradaic efficiencies, high current densities and low overpotentials. The NGQDs show a high total Faradaic efficiency of carbon dioxide reduction of up to 90%, with selectivity for ethylene and ethanol conversions reaching 45%. The C2 and C3 product distribution and production rate for NGQD-catalysed carbon dioxide reduction is comparable to those obtained with copper nanoparticle-based electrocatalysts.
Electroreduction of CO
2
into C2 hydrocarbons and liquid fuels is a promising but challenging energy conversion technology, with copper exhibiting fair selectivity for these products. Here, the authors report that N-doped graphene quantum dots can also catalyze the electrochemical reduction of CO
2
into multi-carbon hydrocarbons and oxygenates.