Probing optical anapoles with fast electron beams

• Published in: Nature communications Vol. 14; no. 1; p. 8478
• Main Authors: Maciel-Escudero, Carlos, Yankovich, Andrew B., Munkhbat, Battulga, Baranov, Denis G., Hillenbrand, Rainer, Olsson, Eva, Aizpurua, Javier, Shegai, Timur O.
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 20-12-2023; Nature Publishing Group; Nature Portfolio
• Subjects: 639/624/399/1098; 639/624/400/1021; Dielectric strength; Electromagnetic radiation; Electron beams; Electron energy loss spectroscopy; Electrons; Energy loss; Excitation; Excitons; Far fields; Humanities and Social Sciences; Hybrids; multidisciplinary; Multipoles; Optics; Radiation; Scanning transmission electron microscopy; Science; Science (multidisciplinary); Spectroscopy; Spectrum analysis; Transmission electron microscopy; Tungsten; Tungsten disulfide
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-023-43813-y

Optical anapoles are intriguing charge-current distributions characterized by a strong suppression of electromagnetic radiation. They originate from the destructive interference of the radiation produced by electric and toroidal multipoles. Although anapoles in dielectric structures have been probed and mapped with a combination of near- and far-field optical techniques, their excitation using fast electron beams has not been explored so far. Here, we theoretically and experimentally analyze the excitation of optical anapoles in tungsten disulfide (WS
2
) nanodisks using Electron Energy Loss Spectroscopy (EELS) in Scanning Transmission Electron Microscopy (STEM). We observe prominent dips in the electron energy loss spectra and associate them with the excitation of optical anapoles and anapole-exciton hybrids. We are able to map the anapoles excited in the WS
2
nanodisks with subnanometer resolution and find that their excitation can be controlled by placing the electron beam at different positions on the nanodisk. Considering current research on the anapole phenomenon, we envision EELS in STEM to become a useful tool for accessing optical anapoles appearing in a variety of dielectric nanoresonators.
Optical anapoles in nanoresonators result in strong suppression of the electromagnetic radiation, which is challenging to detect in ideal settings. Here, the authors show that fast electrons are a powerful tool to circumvent this challenge due to their ability to access dark modes.