Assessment of the Porous Structure and Surface Chemistry of Activated Biocarbons Used for Methylene Blue Adsorption

• Published in: Molecules (Basel, Switzerland) Vol. 28; no. 13; p. 4922
• Main Authors: Charmas, Barbara, Zięzio, Magdalena, Jedynak, Katarzyna
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 22-06-2023; MDPI
• Subjects: Activated carbon; activated carbons; Adsorption; Amorphous materials; Carbon dioxide; Charcoal - chemistry; Energy sources; Kinetics; Low temperature; Methylene blue; Methylene Blue - chemistry; microwave modification; Microwave radiation; Microwaves; organic dye adsorption; physical activation; Pore size; Porosity; porous structure characterization; Pyrolysis; Radiation; Raman spectroscopy; Raw materials; Scanning electron microscopy; Spectroscopy, Fourier Transform Infrared; Steam; Structural stability; Surface chemistry; Temperature; Thermal analysis; Thermal stability; Titration; Water Pollutants, Chemical - chemistry; Wheat bran; X-ray diffraction; Poland; United Kingdom; porous structure characterization; organic dye adsorption; activated carbons; microwave modification; surface chemistry; physical activation
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules28134922

In the presented research, activated carbons from wheat bran were obtained as a result of pyrolysis and physical activation (CO
or/and steam). In addition, the obtained materials were subjected to additional modification with superheated steam using the microwave radiation as an energy source. The detailed materials characterization was performed using low-temperature nitrogen adsorption/desorption, Raman spectroscopy, X-ray diffraction, thermal analysis (TG), Boehm's titration, point of zero charge (pH
), scanning electron microscopy (SEM) and FT-IR/ATR methods. Moreover, the sorption capacity towards methylene blue (MB) was determined. The activated carbons were characterized with a well-developed surface and pore structure (S
= 339.6-594.0 m
/g; V
= 0.157-0.356 cm
/g). Activation in the presence of steam and additional modification with microwave radiation resulted in much better development of the porous structure (S
= 600.4 m
/g; V
= 0.380 cm
/g). The materials were shown to possess amorphous structure and thermal stability up to the temperatures of ~450-500 °C. They have good adsorption capacity towards MB varying from 150 mg/g to 241 mg/g depending on activation manner. The adsorption can be described by the pseudo-second order model (R
= 0.99) and fitted to the Langmuir isotherm.