A Novel Artificial Neuron-Like Gas Sensor Constructed from CuS Quantum Dots/Bi2S3 Nanosheets

• Published in: Nano-micro letters Vol. 14; no. 1; pp. 1 - 15
• Main Authors: Chen, Xinwei, Wang, Tao, Shi, Jia, Lv, Wen, Han, Yutong, Zeng, Min, Yang, Jianhua, Hu, Nantao, Su, Yanjie, Wei, Hao, Zhou, Zhihua, Yang, Zhi, Zhang, Yafei
• Format: Journal Article
• Language: English
• Published: Singapore Springer Nature Singapore 01-12-2022; Springer Nature B.V; Springer Singapore; SpringerOpen
• Subjects: Adsorption; Artificial neuron-like gas sensor; Bismuth sulfides; Charge efficiency; Charge transfer; Charge transport; Copper sulfides; Density; Engineering; Environmental monitoring; Gas sensors; Gases; Heterostructure design; Nanoscale Science and Technology; Nanosheets; Nanotechnology; Nanotechnology and Microengineering; Nitrogen dioxide; Nitrogen dioxide detection; Public health; Quantum dots; Real time; Room temperature; Selectivity; Sensitivity enhancement; Sensors; Simulation; Size effects; Smell; Surface chemistry; Visual signals; Wearable device; Wearable technology; Heterostructure design; Wearable device; Nitrogen dioxide detection; Artificial neuron-like gas sensor
• ISSN: 2311-6706; 2150-5551
• DOI: 10.1007/s40820-021-00740-1

Highlights
An ultra-sensitive capture of NO
2
 molecules and fast charge collection and transfer has been realized by constructing the model of artificial neuron-likegas sensing structure based on CuS quantum dots (QDs)/Bi
2
S
3
 nanosheets (NSs)realizes.
Simulation analysis revealed that CuS QDs and Bi
2
S
3
NSs can be used, respectively, as the main adsorption sites and charge transport pathways, thus leading to a greatly enhanced gas capture ability and charge conduction performance of NO
2
.
Real-time rapid detection of toxic gases at room temperature is particularly important for public health and environmental monitoring. Gas sensors based on conventional bulk materials often suffer from their poor surface-sensitive sites, leading to a very low gas adsorption ability. Moreover, the charge transportation efficiency is usually inhibited by the low defect density of surface-sensitive area than that in the interior. In this work, a gas sensing structure model based on CuS quantum dots/Bi
2
S
3
nanosheets (CuS QDs/Bi
2
S
3
NSs) inspired by artificial neuron network is constructed. Simulation analysis by density functional calculation revealed that CuS QDs and Bi
2
S
3
NSs can be used as the main adsorption sites and charge transport pathways, respectively. Thus, the high-sensitivity sensing of NO
2
can be realized by designing the artificial neuron-like sensor. The experimental results showed that the CuS QDs with a size of about 8 nm are highly adsorbable, which can enhance the NO
2
sensitivity due to the rich sensitive sites and quantum size effect. The Bi
2
S
3
NSs can be used as a charge transfer network channel to achieve efficient charge collection and transmission. The neuron-like sensor that simulates biological smell shows a significantly enhanced response value (3.4), excellent responsiveness (18 s) and recovery rate (338 s), low theoretical detection limit of 78 ppb, and excellent selectivity for NO
2
. Furthermore, the developed wearable device can also realize the visual detection of NO
2
through real-time signal changes.