Platinum-trimer decorated cobalt-palladium core-shell nanocatalyst with promising performance for oxygen reduction reaction

• Published in: Nature communications Vol. 10; no. 1; p. 440
• Main Authors: Dai, Sheng, Chou, Jyh-Pin, Wang, Kuan-Wen, Hsu, Yang-Yang, Hu, Alice, Pan, Xiaoqing, Chen, Tsan-Yao
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 25-01-2019; Nature Publishing Group; Nature Portfolio
• Subjects: 140/146; 147/137; 639/301/299/893; 639/638/161/886; Catalysis; Catalysts; Cathodes; Cell cathodes; Chemical reduction; Cobalt; Decoration; Design engineering; Durability; Electrocatalysts; Fuel cells; Fuel technology; Humanities and Social Sciences; Localization; multidisciplinary; Nuclear fuels; Oxygen; Oxygen reduction reactions; Palladium; Platinum; Science; Science (multidisciplinary); Trimers
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/s41467-019-08323-w

Advanced electrocatalysts with low platinum content, high activity and durability for the oxygen reduction reaction can benefit the widespread commercial use of fuel cell technology. Here, we report a platinum-trimer decorated cobalt-palladium core-shell nanocatalyst with a low platinum loading of only 2.4 wt% for the use in alkaline fuel cell cathodes. This ternary catalyst shows a mass activity that is enhanced by a factor of 30.6 relative to a commercial platinum catalyst, which is attributed to the unique charge localization induced by platinum-trimer decoration. The high stability of the decorated trimers endows the catalyst with an outstanding durability, maintaining decent electrocatalytic activity with no degradation for more than 322,000 potential cycles in alkaline electrolyte. These findings are expected to be useful for surface engineering and design of advanced fuel cell catalysts with atomic-scale platinum decoration.
Fuel cells are promising for converting fuel into electricity, but rely on development of high-performance catalysts for oxygen reduction. Here the authors report a highly durable platinum-trimer decorated cobalt-palladium catalyst with low platinum loading for electrocatalysis of oxygen reduction.