ZnO@C (core@shell) microspheres derived from spent coffee grounds as applicable non-precious electrode material for DMFCs

• Published in: Scientific reports Vol. 7; no. 1; pp. 1738 - 8
• Main Authors: Ghouri, Zafar Khan, Al-Meer, Saeed, Barakat, Nasser A. M., Kim, Hak Yong
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 11-05-2017; Nature Publishing Group; Nature Portfolio
• Subjects: 639/4077; 639/4077/893; Bioelectric Energy Sources; Carbon; Coffee; Coffee - chemistry; Electrochemistry; Electrodes; Elements; Fuel cells; Fuel technology; Humanities and Social Sciences; Methanol; Methanol - chemistry; Microspheres; multidisciplinary; Oxidation; Science; Science (multidisciplinary); Spectrometry, X-Ray Emission; X-Ray Diffraction; Zinc Oxide - chemistry
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-017-01463-3

Although numerous reports have introduced non precious electrocatalysts for methanol oxidation, most of those studies did not consider the corresponding high onset potential which restricts utilization in real fuel cells. In this study, an −90 mV [vs. Ag/AgCl] onset potential non-precious electrocatalyst is introduced as an applicable anode material for the direct methanol fuel cells. Moreover, the proposed material was prepared from a cheap and abundantly existing resource; the spent coffee grounds. Typically, the spent coffee grounds were facilely converted to core@shell (ZnO@C) microspheres through a two-step approach, involving chemical activation and a subsequent calcination at temperature of 700 °C. Activation of the carbon derived from the spent coffee grounds was performed with ZnCl
2
which acts as pore-forming agent as well as a precursor for the ZnO. The structure and morphology were characterized by (XRD), (SEM), and (TEM) analyses while the electrochemical characterizations was evaluated by cyclic voltammetry (CV) technique. Besides the comparatively very low onset potential, the introduced microspheres exhibited relatively high current density; 17 mA/cm
2
. Overall, based on the advantages of the green source of carbon and the good electrocatalytic activity, the spent coffee grounds-derived carbon can be considered a promise anode material for the DMFCs.