Palladium stabilized on poly and mono sulfonamide ligands as novel, simple, effective, and recyclable nano catalysts for C–C cross-coupling reactions

• Published in: Canadian journal of chemistry Vol. 95; no. 10; pp. 1073 - 1080
• Main Authors: Ghorbani-Vaghei, Ramin, Sarmast, Narges
• Format: Journal Article
• Language: English
• Published: Ottawa NRC Research Press 01-10-2017; Canadian Science Publishing NRC Research Press
• Subjects: Antibiotics; Aromatic compounds; catalyseur hétérogène; catalyseurs à base de Pd; Catalysis; Catalysts; Catalytic activity; Chemical properties; Chemical reactions; Chemistry; Cross coupling; C–C coupling reaction; Halides; heterogeneous catalyst; ligand à base de sulfonamide; Ligands; Ligands (Chemistry); Nanoparticles; Observations; Palladium; Pd catalysts; Polymers; polymère sur support; réaction de couplage C–C; sulfonamid ligand; Sulfonamides; supported polymer
• ISSN: 0008-4042; 1480-3291
• DOI: 10.1139/cjc-2017-0353

Poly and mono sulfonamide ligands were successfully used for the stabilization of palladium nanoparticles. The prepared nano catalysts that appeared to be heterogeneous and novel were characterized with various analytical tools. To establish the catalytic activity of the prepared catalysts, they were used in the Suzuki–Miyaura and Sonogashira–Hagihara coupling reactions of aryl halides under low palladium loading conditions. The catalysts showed good stability and could be recovered and reused for seven reaction cycles without significant loss of catalytic activity.