Enhanced materials from nature: nanocellulose from citrus waste

• Published in: Molecules (Basel, Switzerland) Vol. 20; no. 4; pp. 5908 - 5923
• Main Authors: Mariño, Mayra, Lopes da Silva, Lucimara, Durán, Nelson, Tasic, Ljubica
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 03-04-2015; MDPI
• Subjects: Biomass; Cellulose; Cellulose - chemistry; Cellulose - ultrastructure; cellulose crystallinity index; Chemistry; Citrus - chemistry; citrus waste; Crystallinity; Energy consumption; enzymatic hydrolysis; Extraction; Hydrolysis; Lignin; Lignocellulose; Morphology; nanocellulose; Nanocomposites; Nanofibers - chemistry; Nanofibers - ultrastructure; Nanostructure; NMR; Nuclear magnetic resonance; Nuclear Magnetic Resonance, Biomolecular; Porous materials; Raw materials; Resultants; Scanning electron microscopy; Spectroscopy, Fourier Transform Infrared; Tensile strength; Wastes; X-Ray Diffraction; Xanthomonas axonopodis pv. citri; Brazil
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules20045908

Nanocellulose is a relatively inexpensive, highly versatile bio-based renewable material with advantageous properties, including biodegradability and nontoxicity. Numerous potential applications of nanocellulose, such as its use for the preparation of high-performance composites, have attracted much attention from industry. Owing to the low energy consumption and the addition of significant value, nanocellulose extraction from agricultural waste is one of the best alternatives for waste treatment. Different techniques for the isolation and purification of nanocellulose have been reported, and combining these techniques influences the morphology of the resultant fibers. Herein, some of the extraction routes for obtaining nanocellulose from citrus waste are addressed. The morphology of nanocellulose was determined by Scanning Electron Microscopy (SEM) and Field Emission Scanning Electron Microscopy (FESEM), while cellulose crystallinity indexes (CI) from lyophilized samples were determined using solid-state Nuclear Magnetic Resonance (NMR) and X-Ray Diffraction (XRD) measurements. The resultant nanofibers had 55% crystallinity, an average diameter of 10 nm and a length of 458 nm.