Tuning the Composition of Guest Molecules in Clathrate Hydrates: NMR Identification and Its Significance to Gas Storage

• Published in: Chemistry, an Asian journal Vol. 4; no. 8; pp. 1266 - 1274
• Main Authors: Seo, Yutaek, Lee, Jong-Won, Kumar, Rajnish, Moudrakovski, Igor L., Lee, Huen, Ripmeester, John A.
• Format: Journal Article
• Language: English
• Published: Weinheim WILEY-VCH Verlag 03-08-2009; WILEY‐VCH Verlag
• Subjects: clathrates; gas hydrates; natural gas; NMR spectroscopy; storage
• ISSN: 1861-4728; 1861-471X
• DOI: 10.1002/asia.200900087

Gas hydrates represent an attractive way of storing large quantities of gas such as methane and carbon dioxide, although to date there has been little effort to optimize the storage capacity and to understand the trade‐offs between storage conditions and storage capacity. In this work, we present estimates for gas storage based on the ideal structures, and show how these must be modified given the little data available on hydrate composition. We then examine the hypothesis based on solid‐solution theory for clathrate hydrates as to how storage capacity may be improved for structure II hydrates, and test the hypothesis for a structure II hydrate of THF and methane, paying special attention to the synthetic approach used. Phase equilibrium data are used to map the region of stability of the double hydrate in P–T space as a function of the concentration of THF. In situ high‐pressure NMR experiments were used to measure the kinetics of reaction between frozen THF solutions and methane gas, and 13C MAS NMR experiments were used to measure the distribution of the guests over the cage sites. As known from previous work, at high concentrations of THF, methane only occupies the small cages in structure II hydrate, and in accordance with the hypothesis posed, we confirm that methane can be introduced into the large cage of structure II hydrate by lowering the concentration of THF to below 1.0 mol %. We note that in some preparations the cage occupancies appear to fluctuate with time and are not necessarily homogeneous over the sample. Although the tuning mechanism is generally valid, the composition and homogeneity of the product vary with the details of the synthetic procedure. The best results, those obtained from the gas–liquid reaction, are in good agreement with thermodynamic predictions; those obtained for the gas–solid reaction do not agree nearly as well.
Filling in all the blanks: Structure II (sII) double hydrates can be tuned to optimize gas storage conditions by adjusting the concentration of the water‐soluble hydrate former, THF in this study. In situ high‐pressure NMR experiments were used to measure the kinetics of reaction between frozen THF solutions and methane gas, and 13C MAS NMR experiments were used to measure the distribution of the guests over the cage sites.