Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability

• Published in: Scientific reports Vol. 9; no. 1; pp. 10922 - 12
• Main Authors: Lim, Sun Taek, Kim, Ji Hoon, Lee, Chang Yeon, Koo, Sangmo, Jerng, Dong-Wook, Wongwises, Somchai, Ahn, Ho Seon
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 29-07-2019; Nature Publishing Group
• Subjects: 140/146; 639/301; 639/638/549; Adsorbents; Adsorption; Aromatic compounds; Chemical properties; Climate change; Gas detectors; Gases; Global warming; Graphene; Humanities and Social Sciences; multidisciplinary; Organic compounds; Photoelectron spectroscopy; Polypropylene; Powder; Scanning electron microscopy; Science; Science (multidisciplinary); Toluene; VOCs; Volatile organic compounds; Xylene
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-019-47100-z

As novel technologies have been developed, emissions of gases of volatile organic compounds (VOCs) have increased. These affect human health and are destructive to the environment, contributing to global warming. Hence, regulations on the use of volatile organic compounds have been strengthened. Therefore, powerful adsorbents are required for volatile organic compounds gases. In this study, we used graphene powder with a mesoporous structure to adsorb aromatic compounds such as toluene and xylene at various concentrations (30, 50, 100 ppm). The configuration and chemical composition of the adsorbents were characterized using scanning electron microscopy (SEM), N
2
adsorption-desorption isotherm measurements, and X-ray photoelectron spectroscopy (XPS). The adsorption test was carried out using a polypropylene filter, which contained the adsorbents (0.25 g), with analysis performed using a gas detector. Compared to graphite oxide (GO) powder, the specific surface area of thermally expanded graphene powder (TEGP800) increased significantly, to 542 m
2
 g
−1
, and its chemical properties transformed from polar to non-polar. Thermally expanded graphene powder exhibits high adsorption efficiency for toluene (92.7–98.3%) and xylene (96.7–98%) and its reusability is remarkable, being at least 91%.