Spectral Dependence of the Photoplastic Effect in CdZnTe and CdZnTeSe

• Published in: Materials Vol. 14; no. 6; p. 1465
• Main Authors: Franc, Jan, Dědič, Václav, Moravec, Pavel, Rejhon, Martin, Grill, Roman, Elhadidy, Hassan, Šíma, Vladimír, Cieslar, Miroslav, Bratko, Maroš, Roy, Utpal, James, Ralph B
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 17-03-2021; MDPI
• Subjects: Cadmium zinc tellurides; CdZnTe; CdZnTeSe; Dependence; Diamond pyramid hardness; Electric fields; II-VI semiconductors; Illumination; Light; MATERIALS SCIENCE; Photoconductivity; photoplasticity; Point defects; Sensors; Space charge; Spectra; spectral dependence; spectral dependence; CdZnTe; photoplasticity; CdZnTeSe
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma14061465

We studied the spectral dependence of the Vickers microhardness HV0.025 of CdZnTe and CdZnTeSe samples upon illumination and found out that it increases over the entire applied spectral range of 1540-750 nm. We also found out that the photoconductivity and microhardness are correlated. We observed changes in the correlation diagram (change of slope and an abrupt change of HV0.025 at several wavelengths of the illuminating light). Based on measurements of the relative changes of the space charge upon illumination using the Pockels effect, we suggest that the observed spectral dependence of positive photoplastic effect in CdZnTe and CdZnTeSe can be explained by the trapping of photoinduced electrons and holes, which affects the motion of the partial dislocations. The underlying physical explanation relies on the assumption that reconstructed bonds break before dislocation glide.