Materials for lithium recovery from salt lake brine

• Published in: Journal of materials science Vol. 56; no. 1; pp. 16 - 63
• Main Authors: Xu, Ping, Hong, Jun, Qian, Xiaoming, Xu, Zhiwei, Xia, Hong, Tao, Xuchen, Xu, Zhenzhen, Ni, Qing-Qing
• Format: Journal Article
• Language: English
• Published: New York Springer US 01-01-2021; Springer; Springer Nature B.V
• Subjects: Brines; Characterization and Evaluation of Materials; Chemistry and Materials Science; Classical Mechanics; Crystallography and Scattering Methods; Electric industries; Electrodialysis; Industrial applications; Lakes; Lithium; Low cost; Materials recovery; Materials Science; Nanofiltration; Polymer Sciences; Review; Salt lakes; Selectivity; Separation; Solid Mechanics; Solvent extraction
• ISSN: 0022-2461; 1573-4803
• DOI: 10.1007/s10853-020-05019-1

Rapid developments in the electric industry have promoted an increasing demand for lithium resources. Lithium in salt lake brines has emerged as the main source for industrial lithium extraction, owing to its low cost and extensive reserves. The effective separation of Mg
2+
and Li
+
is critical to achieving high recovery efficiency and purity of the final lithium product. This paper summarizes Mg
2+
/Li
+
separation materials and methods in the field of lithium recovery from salt lake brines. The review begins with an introduction to the global distribution and demand for lithium resources, followed by a description of the materials used in various separation techniques, including precipitation, adsorption, solvent extraction, nanofiltration membrane, electrodialysis, and electrochemical methods. A comparison, analysis, and outlook of such methods are comprehensively discussed in terms of principles, mechanisms, synthesis/operation, development, and industrial applications. We conclude with a presentation of challenges and insights into the future directions of lithium extraction from salt lake brines. A combination of the advantages of various materials is the most logical step toward developing novel methods for extracting lithium from brines with high separation selectivity, stability, low cost, and environmentally friendly characteristics.