Equation of State for the Thermodynamic Properties of trans-1,3,3,3-Tetrafluoropropene [R-1234ze(E)]

• Published in: International journal of thermophysics Vol. 37; no. 3; pp. 1 - 16
• Main Authors: Thol, Monika, Lemmon, Eric W.
• Format: Journal Article
• Language: English
• Published: New York Springer US 01-03-2016
• Subjects: Classical Mechanics; Condensed Matter Physics; Density; Equations of state; Industrial Chemistry/Chemical Engineering; Liquids; Mathematical analysis; Physical Chemistry; Physics; Physics and Astronomy; Sound; Thermodynamic properties; Uncertainty; 1; 3; Helmholtz energy; R-1234ze(E); 3-Tetrafluoroprop-1-ene; Thermodynamic properties; Equation of state
• ISSN: 0195-928X; 1572-9567
• DOI: 10.1007/s10765-016-2040-6

An equation of state for the calculation of the thermodynamic properties of the hydrofluoroolefin refrigerant R-1234ze(E) is presented. The equation of state (EOS) is expressed in terms of the Helmholtz energy as a function of temperature and density. The formulation can be used for the calculation of all thermodynamic properties through the use of derivatives of the Helmholtz energy. Comparisons to experimental data are given to establish the uncertainty of the EOS. The equation of state is valid from the triple point (169 K) to 420 K, with pressures to 100 MPa. The uncertainty in density in the liquid and vapor phases is 0.1 % from 200 K to 420 K at all pressures. The uncertainty increases outside of this temperature region and in the critical region. In the gaseous phase, speeds of sound can be calculated with an uncertainty of 0.05 %. In the liquid phase, the uncertainty in speed of sound increases to 0.1 %. The estimated uncertainty for liquid heat capacities is 5 %. The uncertainty in vapor pressure is 0.1 %.