Recent Developments in Chitosan-Based Adsorbents for the Removal of Pollutants from Aqueous Environments

• Published in: Molecules (Basel, Switzerland) Vol. 26; no. 3; p. 594
• Main Authors: da Silva Alves, Daniele C, Healy, Bronach, Pinto, Luiz A de Almeida, Cadaval, Jr, Tito R Sant'Anna, Breslin, Carmel B
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI AG 23-01-2021; MDPI
• Subjects: Activated carbon; adsorbent; Adsorbents; Adsorption; Antibiotics; Aquatic environment; Aqueous environments; Bacteria; Binding sites; Biopolymers; Cadmium; carbon; Cellulose; Charcoal; Chitin; Chitin - chemistry; Chitosan; Chitosan - chemistry; Chromium; Climate change; Composite materials; Contaminants; Crustaceans; Enzymes; Fungi; Graphene; graphene oxide; Graphite - chemistry; Heavy metals; Humans; magnetic separation; Metal ions; Metals, Heavy - chemistry; Nanotechnology; Organic chemistry; Phenols; Pollutant removal; Pollutants; Review; Reviews; Seafood; Silica; Silicon Dioxide - chemistry; Water - chemistry; Water Pollutants, Chemical - chemistry; Water Purification - methods; Water quality; United States > US; magnetic separation; chitosan; graphene oxide; adsorbent; adsorption; heavy metals; carbon; silica; dyes; Langmuir isotherm
• ISSN: 1420-3049; 1420-3049
• DOI: 10.3390/molecules26030594

The quality of water is continuously under threat as increasing concentrations of pollutants escape into the aquatic environment. However, these issues can be alleviated by adsorbing pollutants onto adsorbents. Chitosan and its composites are attracting considerable interest as environmentally acceptable adsorbents and have the potential to remove many of these contaminants. In this review the development of chitosan-based adsorbents is described and discussed. Following a short introduction to the extraction of chitin from seafood wastes, followed by its conversion to chitosan, the properties of chitosan are described. Then, the emerging chitosan/carbon-based materials, including magnetic chitosan and chitosan combined with graphene oxide, carbon nanotubes, biochar, and activated carbon and also chitosan-silica composites are introduced. The applications of these materials in the removal of various heavy metal ions, including Cr(VI), Pb(II), Cd(II), Cu(II), and different cationic and anionic dyes, phenol and other organic molecules, such as antibiotics, are reviewed, compared and discussed. Adsorption isotherms and adsorption kinetics are then highlighted and followed by details on the mechanisms of adsorption and the role of the chitosan and the carbon or silica supports. Based on the reviewed papers, it is clear, that while some challenges remain, chitosan-based materials are emerging as promising adsorbents.